Theoretical studies on the N-containing radicals formed in thermal decompositions of dimethyl- and diethyldiazenes

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Abstract

The geometries and energies of μ1 and μ2 radicals, formed in the thermal reaction of dimethyl- and diethyldiazenes, were investigated by means of UHF-MINDO/3. The stability of μ radicals was found greater than that of allyl radical. The calculated SOMO energies show a lower reactivity in H-abstraction reactions than that of alkyl and allyl radicals.

Original languageEnglish
Pages (from-to)65-69
Number of pages5
JournalReaction Kinetics and Catalysis Letters
Volume40
Issue number1
DOIs
Publication statusPublished - Mar 1 1989

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

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