Theoretical investigation on the concentration dependence of the Landolt time

A. Horváth, I. Nagypál, György Csekõ

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Based on the modified kinetic model of the Landolt and the Dushman reactions published recently, an exact expression has been derived for the concentration dependence of the Landolt time. It is also shown that all the apparently contradictory formulas, regarding the concentration dependence of the Landolt time, reported previously at quite different experimental circumstances can easily be reconciled from the simplification of the newly proposed equation. It also means that the formula derived may satisfactorily be applied to calculate the Landolt time basically with no restrictions for the concentration of the reactants.

Original languageEnglish
Pages (from-to)7868-7872
Number of pages5
JournalJournal of Physical Chemistry A
Volume112
Issue number34
DOIs
Publication statusPublished - Aug 28 2008

Fingerprint

Kinetics
simplification
constrictions
kinetics

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Theoretical investigation on the concentration dependence of the Landolt time. / Horváth, A.; Nagypál, I.; Csekõ, György.

In: Journal of Physical Chemistry A, Vol. 112, No. 34, 28.08.2008, p. 7868-7872.

Research output: Contribution to journalArticle

@article{adda06457fb9495ebff9c6bf97e5e8a4,
title = "Theoretical investigation on the concentration dependence of the Landolt time",
abstract = "Based on the modified kinetic model of the Landolt and the Dushman reactions published recently, an exact expression has been derived for the concentration dependence of the Landolt time. It is also shown that all the apparently contradictory formulas, regarding the concentration dependence of the Landolt time, reported previously at quite different experimental circumstances can easily be reconciled from the simplification of the newly proposed equation. It also means that the formula derived may satisfactorily be applied to calculate the Landolt time basically with no restrictions for the concentration of the reactants.",
author = "A. Horv{\'a}th and I. Nagyp{\'a}l and Gy{\"o}rgy Csek{\~o}",
year = "2008",
month = "8",
day = "28",
doi = "10.1021/jp803790e",
language = "English",
volume = "112",
pages = "7868--7872",
journal = "Journal of Physical Chemistry A",
issn = "1089-5639",
publisher = "American Chemical Society",
number = "34",

}

TY - JOUR

T1 - Theoretical investigation on the concentration dependence of the Landolt time

AU - Horváth, A.

AU - Nagypál, I.

AU - Csekõ, György

PY - 2008/8/28

Y1 - 2008/8/28

N2 - Based on the modified kinetic model of the Landolt and the Dushman reactions published recently, an exact expression has been derived for the concentration dependence of the Landolt time. It is also shown that all the apparently contradictory formulas, regarding the concentration dependence of the Landolt time, reported previously at quite different experimental circumstances can easily be reconciled from the simplification of the newly proposed equation. It also means that the formula derived may satisfactorily be applied to calculate the Landolt time basically with no restrictions for the concentration of the reactants.

AB - Based on the modified kinetic model of the Landolt and the Dushman reactions published recently, an exact expression has been derived for the concentration dependence of the Landolt time. It is also shown that all the apparently contradictory formulas, regarding the concentration dependence of the Landolt time, reported previously at quite different experimental circumstances can easily be reconciled from the simplification of the newly proposed equation. It also means that the formula derived may satisfactorily be applied to calculate the Landolt time basically with no restrictions for the concentration of the reactants.

UR - http://www.scopus.com/inward/record.url?scp=51849129627&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=51849129627&partnerID=8YFLogxK

U2 - 10.1021/jp803790e

DO - 10.1021/jp803790e

M3 - Article

C2 - 18681415

AN - SCOPUS:51849129627

VL - 112

SP - 7868

EP - 7872

JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

SN - 1089-5639

IS - 34

ER -