The synthesis of phosphinates: Traditional versus green chemical approaches

György Keglevich, Nóra Zsuzsa Kiss, Zoltán Mucsi, Erzsébet Jablonkai, Erika Bálint

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Three alternatives are discussed in comparison with the classical esterification of phosphinic chlorides by reaction with alcohols. All novel methods, such as microwave (MW)-assisted direct esterification, MW-assisted phase transfer catalyzed alkylating esterification and the propylphosphonic anhydride-promoted esterification, start from phosphinic acids and offer different advantages and disadvantages. The methods are analyzed from green chemical point of view.

Original languageEnglish
Pages (from-to)103-110
Number of pages8
JournalGreen Processing and Synthesis
Volume3
Issue number2
DOIs
Publication statusPublished - Apr 1 2014

Keywords

  • Green chemistry
  • MW chemistry
  • Phase transfer catalysis
  • Phosphinates
  • Phosphinic acids
  • T3P reagent

ASJC Scopus subject areas

  • Environmental Chemistry
  • Chemical Engineering(all)
  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Industrial and Manufacturing Engineering
  • Health, Toxicology and Mutagenesis

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