The structure of tetramethyl-N,N′-bis-o-tolylcyclodisilazane

L. Bihátsi, P. Hencsei, L. Párkányi

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Tetramethyl-N,N′-bis-o-tolylcyclodisilazane was prepared in order to study the effect of o-substitution of the N-phenyl ring on the molecular structure. A crystal structure determination was carried out together with UV, 1H NMR and MS spectroscopic investigations. The o-tolyl group forms a dihedral angle of -89.6° with the cyclodisilazane ring. This conformation is completely different from that in the two coplanar N-phenyl derivatives previously studied. The molecular geometry and spectroscopic data suggest decreased delocalization, in agreement with the low thermal stability. While the geometry of the cyclodisilazane moiety is unchanged, mass spectroscopic fragmentation indicates that the SiN bonds are weaker than those in N-phenyl derivatives containing phenyl groups coplanar with the four-membered ring.

Original languageEnglish
Pages (from-to)145-151
Number of pages7
JournalJournal of Organometallic Chemistry
Volume219
Issue number2
DOIs
Publication statusPublished - Oct 20 1981

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Fingerprint Dive into the research topics of 'The structure of tetramethyl-N,N′-bis-o-tolylcyclodisilazane'. Together they form a unique fingerprint.

  • Cite this