The stereochemistry of the dichlorocyclopropanation reaction of 2, 5-dihydro-lh-phosphole 1-oxides

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Abstract

The structure of the products from the dichlorocyclopropanation reaction of a number of P-C- and P- O-substituted dihydrophosphole oxides is substantiated and characterized by X-ray analysis and NMR spectroscopy. An explanation is given for the outcome of the reactions yielding the trans-isomer solely or both of the two possible diastereoisomers. The reactivity of the latter two species is briefly discussed.

Original languageEnglish
Pages (from-to)73-79
Number of pages7
JournalPhosphorus, Sulfur, and Silicon and the Related Elements
Volume54
Issue number1-4
DOIs
Publication statusPublished - Sep 1 1990

Keywords

  • X-ray analysis
  • diastereoisomers
  • dichlorocyclopropanation
  • dihydrophosphole oxides
  • reactivity
  • stereoselectivity

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Inorganic Chemistry

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