The resolution and application of P-stereogenic phosphine oxides

Péter Bagi, Réka Herbay, Kinga Juhász, Bence Varga, Elemér Fogassy, G. Keglevich

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Resolution methods involving the formation of diastereomeric complexes were developed for the separation of cyclic P-stereogenic phosphine oxides and phosphinates. These resolution methods are of more general value, as they can be applied also for the enantioseparation of acyclic phosphine oxides. 5- and 6- Membered cyclic phosphine oxides were deoxygenated and then converted to platinum complexes which can be applied as catalysts in enantioselective hydroformylation.

Original languageEnglish
Pages (from-to)1459-1461
Number of pages3
JournalPhosphorus, Sulfur and Silicon and the Related Elements
Volume191
Issue number11-12
DOIs
Publication statusPublished - Dec 1 2016

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phosphine
Oxides
Hydroformylation
Platinum
Catalysts

Keywords

  • Cyclic phosphine oxides
  • hydroformylation
  • optical resolution
  • P-chirality
  • transition metal complexes

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

The resolution and application of P-stereogenic phosphine oxides. / Bagi, Péter; Herbay, Réka; Juhász, Kinga; Varga, Bence; Fogassy, Elemér; Keglevich, G.

In: Phosphorus, Sulfur and Silicon and the Related Elements, Vol. 191, No. 11-12, 01.12.2016, p. 1459-1461.

Research output: Contribution to journalArticle

Bagi, Péter ; Herbay, Réka ; Juhász, Kinga ; Varga, Bence ; Fogassy, Elemér ; Keglevich, G. / The resolution and application of P-stereogenic phosphine oxides. In: Phosphorus, Sulfur and Silicon and the Related Elements. 2016 ; Vol. 191, No. 11-12. pp. 1459-1461.
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