Abstract
The problem of the irreversibility of the adsorption of Cl- ions on platinum has been studied by a tracer method described previously. The mobility of adsorbed Cl- ions has been observed in the following experiments: in the exchange of adsorbed labelled Cl- with non-labelled dissolved Cl- ions; in the desorption caused by the rinsing of the electrode; in the displacement of adsorbed Cl- ions by Br- and I- ions; in the simultaneous adsorption of Cl- ions and other halide ions. In the light of these results the views based on the assumption of irreversibility have been criticized.
| Original language | English |
|---|---|
| Pages (from-to) | 367-373 |
| Number of pages | 7 |
| Journal | Journal of Electroanalytical Chemistry |
| Volume | 83 |
| Issue number | 2 |
| Publication status | Published - Oct 25 1977 |
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ASJC Scopus subject areas
- Electrochemistry
- Analytical Chemistry
- Chemical Engineering(all)
Cite this
The problem of the irreversibility of the adsorption of halides on platinum. / Horányi, G.; Rizmayer, E. M.
In: Journal of Electroanalytical Chemistry, Vol. 83, No. 2, 25.10.1977, p. 367-373.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - The problem of the irreversibility of the adsorption of halides on platinum
AU - Horányi, G.
AU - Rizmayer, E. M.
PY - 1977/10/25
Y1 - 1977/10/25
N2 - The problem of the irreversibility of the adsorption of Cl- ions on platinum has been studied by a tracer method described previously. The mobility of adsorbed Cl- ions has been observed in the following experiments: in the exchange of adsorbed labelled Cl- with non-labelled dissolved Cl- ions; in the desorption caused by the rinsing of the electrode; in the displacement of adsorbed Cl- ions by Br- and I- ions; in the simultaneous adsorption of Cl- ions and other halide ions. In the light of these results the views based on the assumption of irreversibility have been criticized.
AB - The problem of the irreversibility of the adsorption of Cl- ions on platinum has been studied by a tracer method described previously. The mobility of adsorbed Cl- ions has been observed in the following experiments: in the exchange of adsorbed labelled Cl- with non-labelled dissolved Cl- ions; in the desorption caused by the rinsing of the electrode; in the displacement of adsorbed Cl- ions by Br- and I- ions; in the simultaneous adsorption of Cl- ions and other halide ions. In the light of these results the views based on the assumption of irreversibility have been criticized.
UR - http://www.scopus.com/inward/record.url?scp=0006995274&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0006995274&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0006995274
VL - 83
SP - 367
EP - 373
JO - Journal of Electroanalytical Chemistry
JF - Journal of Electroanalytical Chemistry
SN - 0022-0728
IS - 2
ER -