The preparation and electron diffraction study of dichlorogermylene in the vapour phase

E. Vajda, I. Hargittai, M. Kolonits, K. Újszászy, J. Tamás, A. K. Maltsev, R. G. Mikaelian, O. M. Nefedov

Research output: Contribution to journalArticle

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Abstract

A preparative technique for dichlorogermylene for vapour phase investigation is described. An electron diffraction study on a mixture of GeCI2 and GeCl4 in the vapour phase reproduced earlier results for the tetrachloride structure and showed the bond angle to be 107 ± 5° in GeCl2. This result, with its large error limit, is in conformity with structural variations observed for other dihalide molecules.

Original languageEnglish
Pages (from-to)33-44
Number of pages12
JournalJournal of Organometallic Chemistry
Volume105
Issue number1
DOIs
Publication statusPublished - Jan 27 1976

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Electron diffraction
electron diffraction
Vapors
Electrons
vapor phases
tetrachlorides
preparation
diffraction
Molecules
molecules

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

The preparation and electron diffraction study of dichlorogermylene in the vapour phase. / Vajda, E.; Hargittai, I.; Kolonits, M.; Újszászy, K.; Tamás, J.; Maltsev, A. K.; Mikaelian, R. G.; Nefedov, O. M.

In: Journal of Organometallic Chemistry, Vol. 105, No. 1, 27.01.1976, p. 33-44.

Research output: Contribution to journalArticle

Vajda, E. ; Hargittai, I. ; Kolonits, M. ; Újszászy, K. ; Tamás, J. ; Maltsev, A. K. ; Mikaelian, R. G. ; Nefedov, O. M. / The preparation and electron diffraction study of dichlorogermylene in the vapour phase. In: Journal of Organometallic Chemistry. 1976 ; Vol. 105, No. 1. pp. 33-44.
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