The non-existence of a general correction term in continuous heating experiments

L. Gránásy, T. Kemény

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

The simplest possible non-isothermal generalization of the phenomenological isothermal rate equation has been investigated. Its solution, the transformed fraction, C, is a functional of the temperature-time relation, T(t). Previous works, based on the existence of a function-type solution, C(T,t), suggest a way of generalization which is meaningless in the case of a functional solution. A difference is predicted by the function-type description between the kinetic parameters under isothermal and dynamic conditions which is in contradiction with our experimental results on the crystallization of Fe75B25 metallic glass.

Original languageEnglish
Pages (from-to)289-294
Number of pages6
JournalThermochimica Acta
Volume42
Issue number3
DOIs
Publication statusPublished - Dec 30 1980

ASJC Scopus subject areas

  • Instrumentation
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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