The molecular structure of 1-phenylsilatranone

L. Párkányí, P. Hencsei, G. Csonka, I. Kovács

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The crystal structure of 1-phenylsilatranone (C6H5Si(OCOCH2)(OCH2CH2)2N) was determined from X-ray diffraction studies. The asymmetric unit (space group Pna21) is built up of two molecules (Z = 8) with different Si ← N dative bonds of 2.126(3) and 2.111(3) Å. A CNDO/2 calculation was performed with spd base and the results were compared with those obtained for other silatrane and silatranone molecules. Wiberg indices for the transannular donor-acceptor bonds are in linear correlation with the Si ← N distances and they fall in the range of 0.33-0.45.

Original languageEnglish
Pages (from-to)305-311
Number of pages7
JournalJournal of Organometallic Chemistry
Volume329
Issue number3
DOIs
Publication statusPublished - Aug 11 1987

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Molecular Structure
X-Ray Diffraction
Molecular structure
molecular structure
Molecules
molecules
Crystal structure
X ray diffraction
crystal structure
diffraction
x rays
silatrane

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

The molecular structure of 1-phenylsilatranone. / Párkányí, L.; Hencsei, P.; Csonka, G.; Kovács, I.

In: Journal of Organometallic Chemistry, Vol. 329, No. 3, 11.08.1987, p. 305-311.

Research output: Contribution to journalArticle

Párkányí, L. ; Hencsei, P. ; Csonka, G. ; Kovács, I. / The molecular structure of 1-phenylsilatranone. In: Journal of Organometallic Chemistry. 1987 ; Vol. 329, No. 3. pp. 305-311.
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