The molecular structure of 1-fluorosilatrane

L. Párkányí, Pál Hencsei, László Bihátsi, Tibor Müller

Research output: Contribution to journalArticle

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Abstract

The crystal structure of 1-fluorosilatrane has been determined by X-ray diffraction. The N → Si dative bond length is 2.042(1) Å, somewhat longer than that in the 1-chloro derivative (2.023 Å). The carbon atoms linked to nitrogen are disordered. The atoms in the close-packed crystal structure are well fixed and have low thermal motion. Deformation electron density calculations show considerable density in the region between the silicon and nitrogen atoms. A mass spectrometric study indicates a strong SiF bond.

Original languageEnglish
Pages (from-to)1-9
Number of pages9
JournalJournal of Organometallic Chemistry
Volume269
Issue number1
DOIs
Publication statusPublished - Jul 3 1984

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Molecular Structure
Molecular structure
molecular structure
Nitrogen
Atoms
Silicon
Crystal structure
X-Ray Diffraction
atoms
crystal structure
Carbon
Hot Temperature
Bond length
Electrons
nitrogen atoms
Carrier concentration
Derivatives
nitrogen
X ray diffraction
carbon

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

The molecular structure of 1-fluorosilatrane. / Párkányí, L.; Hencsei, Pál; Bihátsi, László; Müller, Tibor.

In: Journal of Organometallic Chemistry, Vol. 269, No. 1, 03.07.1984, p. 1-9.

Research output: Contribution to journalArticle

Párkányí, L. ; Hencsei, Pál ; Bihátsi, László ; Müller, Tibor. / The molecular structure of 1-fluorosilatrane. In: Journal of Organometallic Chemistry. 1984 ; Vol. 269, No. 1. pp. 1-9.
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