The mechanisms of hydrogenolysis and isomerization of oxacycloalkanes on metals. II. New results on the transformations of 2-methyloxacycloalkanes on metals

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Abstract

The hydrogenolysis and isomerization of 2-methyloxacycloalkanes were studied on Pt, Pd, and Ni catalysts in a static microreactor system. The experimental data permitted investigation of the relations between the reaction rate, the regioselectivity, the number of ring atoms, and the nature of the metal catalyst, as well as the postulation of the most probable reaction routes, and a comparison with the patterns of hydrogenolysis of cycloalkanes. The mechanisms of hydrogenolysis of the 2-methyloxacycloalkanes depend on the metal, the number of ring atoms, and the experimental conditions.

Original languageEnglish
Pages (from-to)331-336
Number of pages6
JournalJournal of Catalysis
Volume71
Issue number2
DOIs
Publication statusPublished - 1981

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hydrogenolysis
Hydrogenolysis
Isomerization
isomerization
Metals
Cycloparaffins
metals
catalysts
Regioselectivity
Atoms
Catalysts
rings
Reaction rates
atoms
reaction kinetics
routes

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology

Cite this

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abstract = "The hydrogenolysis and isomerization of 2-methyloxacycloalkanes were studied on Pt, Pd, and Ni catalysts in a static microreactor system. The experimental data permitted investigation of the relations between the reaction rate, the regioselectivity, the number of ring atoms, and the nature of the metal catalyst, as well as the postulation of the most probable reaction routes, and a comparison with the patterns of hydrogenolysis of cycloalkanes. The mechanisms of hydrogenolysis of the 2-methyloxacycloalkanes depend on the metal, the number of ring atoms, and the experimental conditions.",
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AU - Bartók, M.

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AB - The hydrogenolysis and isomerization of 2-methyloxacycloalkanes were studied on Pt, Pd, and Ni catalysts in a static microreactor system. The experimental data permitted investigation of the relations between the reaction rate, the regioselectivity, the number of ring atoms, and the nature of the metal catalyst, as well as the postulation of the most probable reaction routes, and a comparison with the patterns of hydrogenolysis of cycloalkanes. The mechanisms of hydrogenolysis of the 2-methyloxacycloalkanes depend on the metal, the number of ring atoms, and the experimental conditions.

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