The Mechanism of Hydrogenolysis and Isomerization of Oxacycloalkanes on Metals, Part X. Nature of the Active Sites in the Regioselective Hydrogenation of Oxiranes

F. Notheisz, A. Zsigmond, M. Bartók, D. Ostgard, G. V. Smith

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The hydrogenolysis and isomerization of methyloxirane were studied over various Pt catalysts in order to determine the number and nature of the active sites. The steps were found to be the probable active sites and the transformation is structure-sensitive. The regioselectivity is not affected by variation in the catalyst structure, so it is determined by the nature of the metal.

Original languageEnglish
Pages (from-to)153-159
Number of pages7
JournalStudies in Surface Science and Catalysis
Volume59
Issue numberC
DOIs
Publication statusPublished - 1991

Fingerprint

hydrogenolysis
Hydrogenolysis
Epoxy Compounds
Isomerization
isomerization
Hydrogenation
hydrogenation
Metals
catalysts
Regioselectivity
Catalysts
metals
propylene oxide

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Catalysis
  • Physical and Theoretical Chemistry
  • Materials Chemistry
  • Surfaces, Coatings and Films

Cite this

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AU - Zsigmond, A.

AU - Bartók, M.

AU - Ostgard, D.

AU - Smith, G. V.

PY - 1991

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AB - The hydrogenolysis and isomerization of methyloxirane were studied over various Pt catalysts in order to determine the number and nature of the active sites. The steps were found to be the probable active sites and the transformation is structure-sensitive. The regioselectivity is not affected by variation in the catalyst structure, so it is determined by the nature of the metal.

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