The kinetics and mechanism of n‐butyraldehyde photolysis in the vapor phase at 313 nm

S. Förgeteg, T. Bérces, S. Dóbé

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

The photolysis was investigated at 313 nm wavelength, 253–529 K temperatures, and 4 × 10−11‐2 × 10−9 mol·photon/cm2·sec light intensities by determining the quantum yields of 20 reaction products. Primary quantum yields for the seven primary processes and rate constant ratios, rate constants, and Arrhenius parameters for secondary processes were derived on the basis of the suggested reaction scheme. The dependence of the quantum yields of the four major primary processes on experimental conditions was established.

Original languageEnglish
Pages (from-to)219-237
Number of pages19
JournalInternational Journal of Chemical Kinetics
Volume11
Issue number3
DOIs
Publication statusPublished - 1979

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Photolysis
Quantum yield
photolysis
Vapors
vapor phases
Light
Kinetics
Temperature
Rate constants
kinetics
reaction products
luminous intensity
Reaction products
wavelengths
Wavelength
temperature

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

The kinetics and mechanism of n‐butyraldehyde photolysis in the vapor phase at 313 nm. / Förgeteg, S.; Bérces, T.; Dóbé, S.

In: International Journal of Chemical Kinetics, Vol. 11, No. 3, 1979, p. 219-237.

Research output: Contribution to journalArticle

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