The kinetic role of metal ions in environmentally relevant redox reactions of chlorite ion and sulfite ion

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Abstract

A brief survey is given about the reactions of chlorite and sulfite ions with some of the most common transition metal ions. The interpretation of the complex kinetic patterns observed in these systems requires the use of comprehensive data treatment and simultaneous evaluation of all experimental results. In most cases, complex formation reactions are in the core of the catalytic redox cycles initiated by the metal ions. The environmental relevance of the kinetic models proposed for catalytic decomposition of chlorite ion and auto-oxidation of sulfite ion is discussed in detail.

Original languageEnglish
Pages (from-to)47-53
Number of pages7
JournalProgress in Nuclear Energy
Volume37
Issue number1-4
Publication statusPublished - 2001

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Redox reactions
sulfite
chlorite
Metal ions
kinetics
Kinetics
ion
metal
Ions
Transition metals
Decomposition
transition element
Oxidation
decomposition
oxidation

ASJC Scopus subject areas

  • Energy Engineering and Power Technology
  • Nuclear Energy and Engineering

Cite this

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abstract = "A brief survey is given about the reactions of chlorite and sulfite ions with some of the most common transition metal ions. The interpretation of the complex kinetic patterns observed in these systems requires the use of comprehensive data treatment and simultaneous evaluation of all experimental results. In most cases, complex formation reactions are in the core of the catalytic redox cycles initiated by the metal ions. The environmental relevance of the kinetic models proposed for catalytic decomposition of chlorite ion and auto-oxidation of sulfite ion is discussed in detail.",
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AB - A brief survey is given about the reactions of chlorite and sulfite ions with some of the most common transition metal ions. The interpretation of the complex kinetic patterns observed in these systems requires the use of comprehensive data treatment and simultaneous evaluation of all experimental results. In most cases, complex formation reactions are in the core of the catalytic redox cycles initiated by the metal ions. The environmental relevance of the kinetic models proposed for catalytic decomposition of chlorite ion and auto-oxidation of sulfite ion is discussed in detail.

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