The formation and characterization of copper(II) 1,4-benzenediolate and p-semiquinonate complexes

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Abstract

Strongly oxidizing p-quinones such as tetrachloro-1,4-benzoquinone and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone undergo stepwise oxidative addition reactions with copper(I) chloride and bromide in pyridine resulting in copper(II) p-semiquinone and dinuclear copper(II) 1,4-benzenediolate pyridine complexes.

Original languageEnglish
Pages (from-to)51-54
Number of pages4
JournalInorganica Chimica Acta
Volume147
Issue number1
DOIs
Publication statusPublished - Jul 1 1988

Fingerprint

quinones
Copper
Chloranil
copper
Pyridine
Quinones
Addition reactions
pyridines
Bromides
bromides
chlorides
pyridine
cuprous chloride
dichlorodicyanobenzoquinone

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

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title = "The formation and characterization of copper(II) 1,4-benzenediolate and p-semiquinonate complexes",
abstract = "Strongly oxidizing p-quinones such as tetrachloro-1,4-benzoquinone and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone undergo stepwise oxidative addition reactions with copper(I) chloride and bromide in pyridine resulting in copper(II) p-semiquinone and dinuclear copper(II) 1,4-benzenediolate pyridine complexes.",
author = "E. Balogh-Hergovich and G. Speier",
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T1 - The formation and characterization of copper(II) 1,4-benzenediolate and p-semiquinonate complexes

AU - Balogh-Hergovich, E.

AU - Speier, G.

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Y1 - 1988/7/1

N2 - Strongly oxidizing p-quinones such as tetrachloro-1,4-benzoquinone and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone undergo stepwise oxidative addition reactions with copper(I) chloride and bromide in pyridine resulting in copper(II) p-semiquinone and dinuclear copper(II) 1,4-benzenediolate pyridine complexes.

AB - Strongly oxidizing p-quinones such as tetrachloro-1,4-benzoquinone and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone undergo stepwise oxidative addition reactions with copper(I) chloride and bromide in pyridine resulting in copper(II) p-semiquinone and dinuclear copper(II) 1,4-benzenediolate pyridine complexes.

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