An analysis of the excess free energy of solutions of isotopic isomers is given. It is demonstrated that consideration of the contribution of internal degrees of freedom is essential and in the case of solutions of C6H6 C6D6 this term predominates.
|Number of pages||6|
|Journal||Physica A: Statistical Mechanics and its Applications|
|Publication status||Published - May 1978|
ASJC Scopus subject areas
- Statistics and Probability
- Condensed Matter Physics