The equilibrium between acetyl- and methylcobalt tetracarbonyl

Ferenc Ungváry, László Markó

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The equilibrium between acetylcobalt tetracarbonyl on one side and methylcobalt tetracarbonyl and carbon monoxide on the other has been determined in the 0-100°C temperature range. The decarbonylation of acetylcobalt tetracarbonyl is endothermic (ΔH = 11.2±0.6 Kcal mol-1) and is accompanied by a positive entropy change (ΔS = 19.5±2.0 e.u.).

Original languageEnglish
Pages (from-to)211-213
Number of pages3
JournalInorganica Chimica Acta
Volume227
Issue number2
DOIs
Publication statusPublished - Dec 15 1994

Keywords

  • Acetyl complexes
  • Carbonyl complexes
  • Cobalt complexes
  • Equilibrium study
  • Methyl complexes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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