The effects of configuration and ring size on the stability of copper(II) chelates of amino alcohols

K. Trogmayer-Málik, I. Horváth, K. Burger, G. Göndös, I. Gera, M. Bartók

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The protonation constants and the successive stability constants of the copper(II) complexes of a series of amino alcohols were determined by means of potentiometric equilibrium measurements. The data reflected the effects of hydrogen-bonded chelate formation and the size of the ring formed on the protonation constants. The complex formation constants showed the effects of steric factors (cis or trans location of the donor groups, and size of the chelate ring) on the stabilities of copper(II) complexes and on the binding mode (mono- or bifunctional) of the ligands.

Original languageEnglish
Pages (from-to)155-158
Number of pages4
JournalInorganica Chimica Acta
Volume138
Issue number2
DOIs
Publication statusPublished - 1987

Fingerprint

Amino alcohols
Amino Alcohols
Protonation
chelates
Copper
alcohols
copper
rings
configurations
Hydrogen
Ligands
ligands
hydrogen

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

The effects of configuration and ring size on the stability of copper(II) chelates of amino alcohols. / Trogmayer-Málik, K.; Horváth, I.; Burger, K.; Göndös, G.; Gera, I.; Bartók, M.

In: Inorganica Chimica Acta, Vol. 138, No. 2, 1987, p. 155-158.

Research output: Contribution to journalArticle

Trogmayer-Málik, K. ; Horváth, I. ; Burger, K. ; Göndös, G. ; Gera, I. ; Bartók, M. / The effects of configuration and ring size on the stability of copper(II) chelates of amino alcohols. In: Inorganica Chimica Acta. 1987 ; Vol. 138, No. 2. pp. 155-158.
@article{afa7a7dd63174042a581d9e0568604f7,
title = "The effects of configuration and ring size on the stability of copper(II) chelates of amino alcohols",
abstract = "The protonation constants and the successive stability constants of the copper(II) complexes of a series of amino alcohols were determined by means of potentiometric equilibrium measurements. The data reflected the effects of hydrogen-bonded chelate formation and the size of the ring formed on the protonation constants. The complex formation constants showed the effects of steric factors (cis or trans location of the donor groups, and size of the chelate ring) on the stabilities of copper(II) complexes and on the binding mode (mono- or bifunctional) of the ligands.",
author = "K. Trogmayer-M{\'a}lik and I. Horv{\'a}th and K. Burger and G. G{\"o}nd{\"o}s and I. Gera and M. Bart{\'o}k",
year = "1987",
doi = "10.1016/S0020-1693(00)81200-1",
language = "English",
volume = "138",
pages = "155--158",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier BV",
number = "2",

}

TY - JOUR

T1 - The effects of configuration and ring size on the stability of copper(II) chelates of amino alcohols

AU - Trogmayer-Málik, K.

AU - Horváth, I.

AU - Burger, K.

AU - Göndös, G.

AU - Gera, I.

AU - Bartók, M.

PY - 1987

Y1 - 1987

N2 - The protonation constants and the successive stability constants of the copper(II) complexes of a series of amino alcohols were determined by means of potentiometric equilibrium measurements. The data reflected the effects of hydrogen-bonded chelate formation and the size of the ring formed on the protonation constants. The complex formation constants showed the effects of steric factors (cis or trans location of the donor groups, and size of the chelate ring) on the stabilities of copper(II) complexes and on the binding mode (mono- or bifunctional) of the ligands.

AB - The protonation constants and the successive stability constants of the copper(II) complexes of a series of amino alcohols were determined by means of potentiometric equilibrium measurements. The data reflected the effects of hydrogen-bonded chelate formation and the size of the ring formed on the protonation constants. The complex formation constants showed the effects of steric factors (cis or trans location of the donor groups, and size of the chelate ring) on the stabilities of copper(II) complexes and on the binding mode (mono- or bifunctional) of the ligands.

UR - http://www.scopus.com/inward/record.url?scp=0008290672&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0008290672&partnerID=8YFLogxK

U2 - 10.1016/S0020-1693(00)81200-1

DO - 10.1016/S0020-1693(00)81200-1

M3 - Article

VL - 138

SP - 155

EP - 158

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

IS - 2

ER -