The effect of parity violation on kinetic models of enantioselective autocatalysis

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Abstract

A detailed analysis of enantioselective autocatalytic reaction models is carried out using both deterministic and stochastic approaches. The models include the small differences between the total energies of enantiomers (ΔEPV ∼10-13 J mol-1) that arise due to parity violation. Different possible orders of autocatalysis are considered, and the reasons why the predictions of the stochastic and deterministic approaches are different under certain conditions are explored. The continuous time discrete state (CDS) stochastic approach is clearly superior to the deterministic approach. It is concluded that the small difference between enantiomers caused by ΔEPV cannot be amplified under conditions reasonable for the generation of biological chirality. It also seems highly unlikely that biological chirality was determined by any intrinsic difference between enantiomers.

Original languageEnglish
Pages (from-to)6134-6141
Number of pages8
JournalPhysical Chemistry Chemical Physics
Volume9
Issue number46
DOIs
Publication statusPublished - Dec 1 2007

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ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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