The effect of ionic environment on the adsorption of phenol

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

The effect of the ionic environment on the adsorption of phenol from aqueous solutions was investigated in a predominantly microporous carbon and in a commercial carbon designed for wastewater treatment. It was found that not only the pH of the solution but also the method of its setting affects the adsorption capacity. Setting the pH with a buffer solution instead of HCl/NaOH results in a reduced adsorption capacity, owing to the increased number of competing species for adsorption sites, and also to pore blocking. The latter is less critical for the commercial carbon with wider pores. Thermal desorption of phenol exhibits an even stronger dependence on pH setting than adsorption. Upon heating, a mass equivalent to 10-35% of the adsorbed phenol is retained by the surface as a carbon-rich residue, which may modify not only the chemistry but also the pore volume and the pore size distribution of the carbon.

Original languageEnglish
Title of host publicationColloids for Nano- and Biotechnology
EditorsZoltan Horvolgyi, Eva Kiss
Pages148-156
Number of pages9
DOIs
Publication statusPublished - Dec 1 2008

Publication series

NameProgress in Colloid and Polymer Science
Volume135
ISSN (Print)0340-255X

Keywords

  • Activated carbon
  • Adsorption/desorption
  • Surface properties
  • Thermal analysis
  • pH dependence

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Polymers and Plastics
  • Colloid and Surface Chemistry
  • Materials Chemistry

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  • Cite this

    Tóth, A., Novák, C., & László, K. (2008). The effect of ionic environment on the adsorption of phenol. In Z. Horvolgyi, & E. Kiss (Eds.), Colloids for Nano- and Biotechnology (pp. 148-156). (Progress in Colloid and Polymer Science; Vol. 135). https://doi.org/10.1007/2882-2008-105