The crystal structure of 1-phenylcarbasilatrane

P. Hencsei, L. Kovács, L. Párkányi

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Abstract

The crystal structure of 1-phenylcarbasilatrane, [PhSi(OCH2CH2)2(CH2CH2CH2)N], has been determined by X-ray diffraction. The Si ← N dative bond length is 2.291(1) Å, which is 0.13 Å longer than the mean value found in the phenylsilatrane modifications. The conformation and the geometry of the carbasilatrane group is fairly similar to those of the silatrane moiety observed in normal silatranes.

Original languageEnglish
Pages (from-to)185-190
Number of pages6
JournalJournal of Organometallic Chemistry
Volume293
Issue number2
DOIs
Publication statusPublished - Sep 24 1985

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ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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