The crystal structure of 1-phenylcarbasilatrane

P. Hencsei, L. Kovács, L. Párkányí

Research output: Contribution to journalArticle

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Abstract

The crystal structure of 1-phenylcarbasilatrane, [PhSi(OCH2CH2)2(CH2CH2CH2)N], has been determined by X-ray diffraction. The Si ← N dative bond length is 2.291(1) Å, which is 0.13 Å longer than the mean value found in the phenylsilatrane modifications. The conformation and the geometry of the carbasilatrane group is fairly similar to those of the silatrane moiety observed in normal silatranes.

Original languageEnglish
Pages (from-to)185-190
Number of pages6
JournalJournal of Organometallic Chemistry
Volume293
Issue number2
DOIs
Publication statusPublished - Sep 24 1985

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Bond length
Conformations
Crystal structure
X ray diffraction
crystal structure
Geometry
geometry
diffraction
X-Ray Diffraction
x rays
silatrane

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

The crystal structure of 1-phenylcarbasilatrane. / Hencsei, P.; Kovács, L.; Párkányí, L.

In: Journal of Organometallic Chemistry, Vol. 293, No. 2, 24.09.1985, p. 185-190.

Research output: Contribution to journalArticle

Hencsei, P. ; Kovács, L. ; Párkányí, L. / The crystal structure of 1-phenylcarbasilatrane. In: Journal of Organometallic Chemistry. 1985 ; Vol. 293, No. 2. pp. 185-190.
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