The chlorination of indoles by copper(II) chloride

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Abstract

The reaction of indoles with copper(II) chloride has been studied in acetonitrile. At low copper(II):indole ratios, dimers are formed in the presence of dioxygen, oxygenated products are obtained, and at large copper(II):indole ratios, pyrrole ring-chlorinated products are formed in yields of up to 92%. The reactions are postulated to proceed via the radical cations of the indoles formed in an electron-transfer reaction.

Original languageEnglish
Pages (from-to)2305-2308
Number of pages4
JournalJournal of the Chemical Society, Perkin Transactions 1
DOIs
Publication statusPublished - 1986

ASJC Scopus subject areas

  • Chemistry(all)

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