The cheletropic reaction of coordinated o-benzoquinone diimines with triphenylphosphine

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2 Citations (Scopus)

Abstract

Coordinated o-benzoquinone diimine and 4-methyl-o-benzoquinone diimine in [Co(diimine)3JPF6 (1) undergo facile cheletropic reaction with triphenylphosphine to give first 2, 3-dihydro-l, 3, 2-λ5-benzo-diazaphospholes (2), which on decyclization result in the equilibrium products N-(2-aminophenyl)iminotriphenylphosphorane (3a) and N-(2-amino-4-methylphenyl)iminotriphenylphos-phorane (3b) respectively in moderate yields.

Original languageEnglish
Pages (from-to)223-225
Number of pages3
JournalPhosphorus, Sulfur and Silicon and Related Elements
Volume48
Issue number1-4
DOIs
Publication statusPublished - Mar 1 1990

Keywords

  • 1, 4-Cycloaddition
  • benzodiazaphosphole
  • cheletropic reaction
  • iminophosphorane
  • o-benzoquinone diimine

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Organic Chemistry

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