Tetrahydro‐2‐thioxo‐2H‐1,3,5‐thiadiazin‐4‐ones and their derivatives representing a novel heterocyclic ring system

Iván Bélai, P. Sohár, Kazuyuki Maekawa, L. Párkányí, GyÖRgy Matolcsy

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Abstract

The cyclization reaction between N‐substituted dithiocarbamates (1) and N‐substituted N‐chloromethylcarbamoyl chlorides (2) gives 3,5‐disubstituted tetrahydro‐2‐thioxo‐2H‐1,3,5‐thiadiazin‐4‐ones (3). In order to decide among the theoretically possible structures 3‐5, the compounds 6a,b, containing a thioxo group instead of an oxo group as in 3a,b, as well as the S‐oxide derivative of 3a was also established by X‐ray structure determination.

Original languageEnglish
Pages (from-to)283-286
Number of pages4
JournalJournal of Heterocyclic Chemistry
Volume18
Issue number2
DOIs
Publication statusPublished - 1981

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ASJC Scopus subject areas

  • Organic Chemistry

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