Systematic investigation of the near ultraviolet spectra of chlorothiophenes

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The near ultraviolet (UV) spectra of all chlorothiophenes have been investigated in vapour phase and n-hexane solution. The Rydberg bands are shown to obliterate in condensed phase spectra and have an almost constant term value throughout the series of the investigated compounds. In order to assign the valence transitions CNDO/S calculations were carried out. The order of the transitions has been shown to be π4*←π3, π4*←π2 and RS←π3 in each compound.

Original languageEnglish
Pages (from-to)161-164
Number of pages4
JournalActa Physica Hungarica
Volume63
Issue number1-2
DOIs
Publication statusPublished - Mar 1988

Fingerprint

ultraviolet spectra
vapor phases
valence

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Systematic investigation of the near ultraviolet spectra of chlorothiophenes. / Nyulászi, L.; Veszprémi, T.

In: Acta Physica Hungarica, Vol. 63, No. 1-2, 03.1988, p. 161-164.

Research output: Contribution to journalArticle

@article{2c91ca2a2b744bf39f1e7d1a8cd43ea6,
title = "Systematic investigation of the near ultraviolet spectra of chlorothiophenes",
abstract = "The near ultraviolet (UV) spectra of all chlorothiophenes have been investigated in vapour phase and n-hexane solution. The Rydberg bands are shown to obliterate in condensed phase spectra and have an almost constant term value throughout the series of the investigated compounds. In order to assign the valence transitions CNDO/S calculations were carried out. The order of the transitions has been shown to be π4*←π3′, π4*←π2′ and RS←π3 in each compound.",
author = "L. Nyul{\'a}szi and T. Veszpr{\'e}mi",
year = "1988",
month = "3",
doi = "10.1007/BF03155768",
language = "English",
volume = "63",
pages = "161--164",
journal = "Acta Physica Hungarica",
issn = "0231-4428",
publisher = "Akademiai Kiado",
number = "1-2",

}

TY - JOUR

T1 - Systematic investigation of the near ultraviolet spectra of chlorothiophenes

AU - Nyulászi, L.

AU - Veszprémi, T.

PY - 1988/3

Y1 - 1988/3

N2 - The near ultraviolet (UV) spectra of all chlorothiophenes have been investigated in vapour phase and n-hexane solution. The Rydberg bands are shown to obliterate in condensed phase spectra and have an almost constant term value throughout the series of the investigated compounds. In order to assign the valence transitions CNDO/S calculations were carried out. The order of the transitions has been shown to be π4*←π3′, π4*←π2′ and RS←π3 in each compound.

AB - The near ultraviolet (UV) spectra of all chlorothiophenes have been investigated in vapour phase and n-hexane solution. The Rydberg bands are shown to obliterate in condensed phase spectra and have an almost constant term value throughout the series of the investigated compounds. In order to assign the valence transitions CNDO/S calculations were carried out. The order of the transitions has been shown to be π4*←π3′, π4*←π2′ and RS←π3 in each compound.

UR - http://www.scopus.com/inward/record.url?scp=77951512806&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77951512806&partnerID=8YFLogxK

U2 - 10.1007/BF03155768

DO - 10.1007/BF03155768

M3 - Article

VL - 63

SP - 161

EP - 164

JO - Acta Physica Hungarica

JF - Acta Physica Hungarica

SN - 0231-4428

IS - 1-2

ER -