Synthetic, structural and theoretical studies on new aromatic 1,2,4- azadiphosphole ring systems: Crystal and molecular structure of P2C2Bu(t)2NPh

F. Geoffrey N Cloke, Peter B. Hitchcock, John F. Nixon, D. James Wilson, Frank Tabellion, Uwe Fischbeck, Fritz Preuss, Manfred Regitz, L. Nyulászi

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Two different synthetic routes to the new aromatic 1,2,4-aza-diphosphole ring system P2C2Bu(t)2NR (R = Pr(i), Pr, Ph, MeC6H4, Bu(t)CH2 and cyclohexyl) are presented and the planar structure of P2C2Bu(t)2NPh, established by a single crystal X-ray diffraction study, is in good agreement with theoretical calculations at the B3LYP/6-311G* level on the parent P2C2H2NH ring.

Original languageEnglish
Pages (from-to)2363-2364
Number of pages2
JournalChemical Communications
Issue number23
Publication statusPublished - Dec 7 1999

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Molecular structure
Crystal structure
Single crystals
X ray diffraction

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Synthetic, structural and theoretical studies on new aromatic 1,2,4- azadiphosphole ring systems : Crystal and molecular structure of P2C2Bu(t)2NPh. / Cloke, F. Geoffrey N; Hitchcock, Peter B.; Nixon, John F.; Wilson, D. James; Tabellion, Frank; Fischbeck, Uwe; Preuss, Fritz; Regitz, Manfred; Nyulászi, L.

In: Chemical Communications, No. 23, 07.12.1999, p. 2363-2364.

Research output: Contribution to journalArticle

Cloke, FGN, Hitchcock, PB, Nixon, JF, Wilson, DJ, Tabellion, F, Fischbeck, U, Preuss, F, Regitz, M & Nyulászi, L 1999, 'Synthetic, structural and theoretical studies on new aromatic 1,2,4- azadiphosphole ring systems: Crystal and molecular structure of P2C2Bu(t)2NPh', Chemical Communications, no. 23, pp. 2363-2364.
Cloke, F. Geoffrey N ; Hitchcock, Peter B. ; Nixon, John F. ; Wilson, D. James ; Tabellion, Frank ; Fischbeck, Uwe ; Preuss, Fritz ; Regitz, Manfred ; Nyulászi, L. / Synthetic, structural and theoretical studies on new aromatic 1,2,4- azadiphosphole ring systems : Crystal and molecular structure of P2C2Bu(t)2NPh. In: Chemical Communications. 1999 ; No. 23. pp. 2363-2364.
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