Synthesis, structure and spectral properties of a novel stable homoleptic iron(II) complex of 1,3-bis(2′-pyridylimino)isoindoline, Fe(ind) 2

E. Balogh-Hergovich, G. Speier, Marius Réglier, Michel Giorgi, E. Kuzmann, A. Vértes

Research output: Contribution to journalArticle

42 Citations (Scopus)

Abstract

Reaction of two molar equivalents of 1,3-bis(2′-pyridylimino) isoindoline (indH) and a solution of Fe(ClO4)2 in acetonitrile resulted in the formation of a stable homoleptic iron(II) complex without additional solvent coordination. The composition and molecular structure of Fe(ind)2 (2) was fully determined by IR, UV-vis, Mössbauer and X-ray crystal analysis. The complex has an octahedral FeN6 core with high-spin iron(II).

Original languageEnglish
Pages (from-to)457-459
Number of pages3
JournalInorganic Chemistry Communications
Volume8
Issue number5
DOIs
Publication statusPublished - May 2005

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Iron
iron
synthesis
Molecular Structure
Acetonitrile
Molecular structure
acetonitrile
molecular structure
X-Rays
X rays
Crystals
Chemical analysis
crystals
x rays
perchlorate

Keywords

  • Crystal structure
  • Iron complex
  • Isoindoline
  • Mössbauer spectra
  • Tridentate ligand

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

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title = "Synthesis, structure and spectral properties of a novel stable homoleptic iron(II) complex of 1,3-bis(2′-pyridylimino)isoindoline, Fe(ind) 2",
abstract = "Reaction of two molar equivalents of 1,3-bis(2′-pyridylimino) isoindoline (indH) and a solution of Fe(ClO4)2 in acetonitrile resulted in the formation of a stable homoleptic iron(II) complex without additional solvent coordination. The composition and molecular structure of Fe(ind)2 (2) was fully determined by IR, UV-vis, M{\"o}ssbauer and X-ray crystal analysis. The complex has an octahedral FeN6 core with high-spin iron(II).",
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author = "E. Balogh-Hergovich and G. Speier and Marius R{\'e}glier and Michel Giorgi and E. Kuzmann and A. V{\'e}rtes",
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TY - JOUR

T1 - Synthesis, structure and spectral properties of a novel stable homoleptic iron(II) complex of 1,3-bis(2′-pyridylimino)isoindoline, Fe(ind) 2

AU - Balogh-Hergovich, E.

AU - Speier, G.

AU - Réglier, Marius

AU - Giorgi, Michel

AU - Kuzmann, E.

AU - Vértes, A.

PY - 2005/5

Y1 - 2005/5

N2 - Reaction of two molar equivalents of 1,3-bis(2′-pyridylimino) isoindoline (indH) and a solution of Fe(ClO4)2 in acetonitrile resulted in the formation of a stable homoleptic iron(II) complex without additional solvent coordination. The composition and molecular structure of Fe(ind)2 (2) was fully determined by IR, UV-vis, Mössbauer and X-ray crystal analysis. The complex has an octahedral FeN6 core with high-spin iron(II).

AB - Reaction of two molar equivalents of 1,3-bis(2′-pyridylimino) isoindoline (indH) and a solution of Fe(ClO4)2 in acetonitrile resulted in the formation of a stable homoleptic iron(II) complex without additional solvent coordination. The composition and molecular structure of Fe(ind)2 (2) was fully determined by IR, UV-vis, Mössbauer and X-ray crystal analysis. The complex has an octahedral FeN6 core with high-spin iron(II).

KW - Crystal structure

KW - Iron complex

KW - Isoindoline

KW - Mössbauer spectra

KW - Tridentate ligand

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JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

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