Synthesis, Optical, and Redox Properties of Regioisomeric Benzoheterocycles-Fused Pyrene

Anabella Mocanu, Rózsa Szucs, Elsa Caytan, Thierry Roisnel, Vincent Dorcet, Pierre Antoine Bouit, László Nyulászi, Muriel Hissler

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2 Citations (Scopus)

Abstract

A new synthetic route toward the synthesis of benzo[b]phospholes- and benzo[b]siloles-fused pyrenes using a transition metal-catalyzed C-H bond activation is described. The compounds were fully characterized including X-ray diffraction. A combined experimental and theoretical study shows that both the heteroatom and the substitution pattern impact the optical and redox properties.

Original languageEnglish
Pages (from-to)957-962
Number of pages6
JournalJournal of Organic Chemistry
Volume84
Issue number2
DOIs
Publication statusPublished - Jan 18 2019

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ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Mocanu, A., Szucs, R., Caytan, E., Roisnel, T., Dorcet, V., Bouit, P. A., Nyulászi, L., & Hissler, M. (2019). Synthesis, Optical, and Redox Properties of Regioisomeric Benzoheterocycles-Fused Pyrene. Journal of Organic Chemistry, 84(2), 957-962. https://doi.org/10.1021/acs.joc.8b02884