Synthesis, optical and electroanalytical characterizations of a thiacalix[4](N-phenylazacrown-5)ether-BODIPY ionophore

Viktor Csokai, Mihály Kádár, Diem Lan Ha Mai, Olívia Varga, K. Tóth, M. Kubinyi, A. Grün, I. Bitter

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Novel fluorogenic 1,3-alt thiacalix[4](N-phenylazacrown-5)ether ionophore has been synthesized by conjugation of the N-phenyl group with borondipyrromethene (BODIPY) fluorophore moiety. The ionophore exhibits pronounced off-on type fluorescent responses to some transition metal ions, in particular to Cu2+. In a PVC membrane electrode, distinct Ag+ selectivity was observed in potentiometric transduction.

Original languageEnglish
Pages (from-to)1058-1063
Number of pages6
JournalTetrahedron
Volume64
Issue number6
DOIs
Publication statusPublished - Feb 4 2008

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Ionophores
Ether
Fluorophores
Polyvinyl Chloride
Transition metals
Metal ions
Electrodes
Metals
Ions
Membranes

Keywords

  • BODIPY
  • Complexation
  • Fluorescence
  • Ion selectivity
  • ISE
  • Thiacalix[4]crowns

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Synthesis, optical and electroanalytical characterizations of a thiacalix[4](N-phenylazacrown-5)ether-BODIPY ionophore. / Csokai, Viktor; Kádár, Mihály; Ha Mai, Diem Lan; Varga, Olívia; Tóth, K.; Kubinyi, M.; Grün, A.; Bitter, I.

In: Tetrahedron, Vol. 64, No. 6, 04.02.2008, p. 1058-1063.

Research output: Contribution to journalArticle

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AU - Kádár, Mihály

AU - Ha Mai, Diem Lan

AU - Varga, Olívia

AU - Tóth, K.

AU - Kubinyi, M.

AU - Grün, A.

AU - Bitter, I.

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