Synthesis of the first amine-cyanocarboxyboranes, isoelectronic analogues of α-cyanocarboxylic acids

Béla Györi, Z. Berente, R. Király, István Lázár

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The first amine-cyanocarboxyboranes and their esters are synthesized from trimethylamine-bromo(methoxy-carbonyl)boranes with tetrabutylammonium cyanide, followed by amine exchange reactions and acidic hydrolysis; pKa values of "boracyanocarboxylic acids" are determined and their stability in acidic medium examined.

Original languageEnglish
Pages (from-to)300-301
Number of pages2
JournalJournal of the Chemical Society, Perkin Transactions 1
Issue number3
Publication statusPublished - 2002

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Amines
Boranes
Acids
Hydrolysis
Esters
tetrabutylammonium
trimethylamine

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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AU - Györi, Béla

AU - Berente, Z.

AU - Király, R.

AU - Lázár, István

PY - 2002

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AB - The first amine-cyanocarboxyboranes and their esters are synthesized from trimethylamine-bromo(methoxy-carbonyl)boranes with tetrabutylammonium cyanide, followed by amine exchange reactions and acidic hydrolysis; pKa values of "boracyanocarboxylic acids" are determined and their stability in acidic medium examined.

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JO - Journal of the Chemical Society, Perkin Transactions 1

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