Synthesis of six-membered silaheterocycles by the ring enlargement of 1,1-diphenyl-1-silacyclopent-3-ene

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Abstract

Silabicyclo[3.1.0]hexane 2 obtained from silacyclopent-3-ene 1 by dichlorocarbene addition is useful in the synthesis of ring-expanded products, such as silacyclohexa-2,4-diene 3 and 5-alkoxysilacyclohex-3-enes 5. Catalytic hydrogenation of compound 3 affords silacyclohexane 4. The new heterocycles are characterized by 13C and 1H NMR, as well as mass spectroscopic data.

Original languageEnglish
Pages (from-to)171-175
Number of pages5
JournalHeteroatom Chemistry
Volume10
Issue number2
DOIs
Publication statusPublished - Jan 1 1999

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ASJC Scopus subject areas

  • Chemistry(all)

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