Synthesis of open metal carbonyl cluster compounds. The reactions of closo-sulfido metal carbonyl cluster compounds with H2S. Synthesis and crystal and molecular structure of H2Os5(CO)143-S)2

Richard D. Adams, I. Horváth, Li Wu Yang

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15 Citations (Scopus)

Abstract

The reactions of the closo-sulfido osmium carbonyl cluster compounds Os4(CO)123-S), I, and Os5(CO)154-S), II, with H2S yield the open cluster compounds H2Os4(CO)123-S)2, III, and H2Os5(CO)143-S)2, IV, in yields of 55% and 94%, respectively. In each reaction one H2S molecule has been converted into a triply bridging sulfido ligand and two hydride ligands.

Original languageEnglish
Pages (from-to)1257-1258
Number of pages2
JournalOrganometallics
Volume2
Issue number9
Publication statusPublished - 1983

Fingerprint

Molecular structure
molecular structure
Crystal structure
Metals
Ligands
Osmium
ligands
crystal structure
osmium
open clusters
synthesis
Hydrides
metals
hydrides
Molecules
molecules

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

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title = "Synthesis of open metal carbonyl cluster compounds. The reactions of closo-sulfido metal carbonyl cluster compounds with H2S. Synthesis and crystal and molecular structure of H2Os5(CO)14(μ3-S)2",
abstract = "The reactions of the closo-sulfido osmium carbonyl cluster compounds Os4(CO)12(μ3-S), I, and Os5(CO)15(μ4-S), II, with H2S yield the open cluster compounds H2Os4(CO)12(μ3-S)2, III, and H2Os5(CO)14(μ3-S)2, IV, in yields of 55{\%} and 94{\%}, respectively. In each reaction one H2S molecule has been converted into a triply bridging sulfido ligand and two hydride ligands.",
author = "Adams, {Richard D.} and I. Horv{\'a}th and Yang, {Li Wu}",
year = "1983",
language = "English",
volume = "2",
pages = "1257--1258",
journal = "Organometallics",
issn = "0276-7333",
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T1 - Synthesis of open metal carbonyl cluster compounds. The reactions of closo-sulfido metal carbonyl cluster compounds with H2S. Synthesis and crystal and molecular structure of H2Os5(CO)14(μ3-S)2

AU - Adams, Richard D.

AU - Horváth, I.

AU - Yang, Li Wu

PY - 1983

Y1 - 1983

N2 - The reactions of the closo-sulfido osmium carbonyl cluster compounds Os4(CO)12(μ3-S), I, and Os5(CO)15(μ4-S), II, with H2S yield the open cluster compounds H2Os4(CO)12(μ3-S)2, III, and H2Os5(CO)14(μ3-S)2, IV, in yields of 55% and 94%, respectively. In each reaction one H2S molecule has been converted into a triply bridging sulfido ligand and two hydride ligands.

AB - The reactions of the closo-sulfido osmium carbonyl cluster compounds Os4(CO)12(μ3-S), I, and Os5(CO)15(μ4-S), II, with H2S yield the open cluster compounds H2Os4(CO)12(μ3-S)2, III, and H2Os5(CO)14(μ3-S)2, IV, in yields of 55% and 94%, respectively. In each reaction one H2S molecule has been converted into a triply bridging sulfido ligand and two hydride ligands.

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