Synthesis of nitroxide-annulated carbocycles and heterocycles

T. Kalai, Balázs Bognár, Dániel Zsolnai, Z. Berente, K. Hideg

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

New, pyrroline nitroxide annulated lactones, polycycles, and maleimide were synthesized by classical and microwave-assisted methodology. We report the application of the metathesis reaction in the presence of nitroxide yielding a pyrroline nitroxide condensed 1,4-benzoquinone as a paramagnetic dienophile. The formation of the isoselenazolone-fused pyrroline ring system was examined and different reactivity was observed with pyrrolin-1-oxyl and pyrroline derivatives.

Original languageEnglish
Article numberSS-2012-N0671-OP
Pages (from-to)3655-3660
Number of pages6
JournalSynthesis
Volume44
Issue number23
DOIs
Publication statusPublished - 2012

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Microwaves
Derivatives
Lactones
pyrroline

Keywords

  • free radicals
  • heterocycles
  • lactones
  • metathesis
  • quinones

ASJC Scopus subject areas

  • Organic Chemistry
  • Catalysis

Cite this

Synthesis of nitroxide-annulated carbocycles and heterocycles. / Kalai, T.; Bognár, Balázs; Zsolnai, Dániel; Berente, Z.; Hideg, K.

In: Synthesis, Vol. 44, No. 23, SS-2012-N0671-OP, 2012, p. 3655-3660.

Research output: Contribution to journalArticle

Kalai, T. ; Bognár, Balázs ; Zsolnai, Dániel ; Berente, Z. ; Hideg, K. / Synthesis of nitroxide-annulated carbocycles and heterocycles. In: Synthesis. 2012 ; Vol. 44, No. 23. pp. 3655-3660.
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