Synthesis of new optically active pyridino- and pyridono-18-crown-6 type ligands containing four lipophilic chains

János Gerencsér, Nikoletta Báthori, Mátyás Czugler, Péter Huszthy, Mihály Nógrádi

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Highly lipophilic enantiomerically pure pyridino- and pyridono-18-crown-6 type ligands containing four stereogenic centers to which butyl or butoxymethyl groups are attached have been synthesized. X-Ray analysis of the (R)-1-phenylethylammonium and benzylammonium perchlorate complexes of the unsubstituted pyridono ligand revealed, that, in contrast to the free ligand, in the complex the hydroxypyridine tautomer is present.

Original languageEnglish
Pages (from-to)2803-2811
Number of pages9
JournalTetrahedron Asymmetry
Volume14
Issue number18
DOIs
Publication statusPublished - Sep 19 2003

    Fingerprint

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this