Synthesis of new optically active pyridino- and pyridono-18-crown-6 type ligands containing four lipophilic chains

János Gerencsér, Nikoletta Báthori, M. Czugler, P. Huszthy, Mihály Nógrádi

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Highly lipophilic enantiomerically pure pyridino- and pyridono-18-crown-6 type ligands containing four stereogenic centers to which butyl or butoxymethyl groups are attached have been synthesized. X-Ray analysis of the (R)-1-phenylethylammonium and benzylammonium perchlorate complexes of the unsubstituted pyridono ligand revealed, that, in contrast to the free ligand, in the complex the hydroxypyridine tautomer is present.

Original languageEnglish
Pages (from-to)2803-2811
Number of pages9
JournalTetrahedron Asymmetry
Volume14
Issue number18
DOIs
Publication statusPublished - Sep 19 2003

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Ligands
ligands
synthesis
tautomers
X ray analysis
perchlorates
X-Rays
18-crown-6
x rays
hydroxypyridines
perchlorate

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry
  • Materials Chemistry
  • Drug Discovery

Cite this

Synthesis of new optically active pyridino- and pyridono-18-crown-6 type ligands containing four lipophilic chains. / Gerencsér, János; Báthori, Nikoletta; Czugler, M.; Huszthy, P.; Nógrádi, Mihály.

In: Tetrahedron Asymmetry, Vol. 14, No. 18, 19.09.2003, p. 2803-2811.

Research output: Contribution to journalArticle

Gerencsér, János ; Báthori, Nikoletta ; Czugler, M. ; Huszthy, P. ; Nógrádi, Mihály. / Synthesis of new optically active pyridino- and pyridono-18-crown-6 type ligands containing four lipophilic chains. In: Tetrahedron Asymmetry. 2003 ; Vol. 14, No. 18. pp. 2803-2811.
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