Synthesis of methyl (d-glycopyranosyl azide) uronates

Zoltán Györgydeák, Joachim Thiem

Research output: Contribution to journalArticle

75 Citations (Scopus)

Abstract

Sodium hypochlorite oxidation catalysed by 2,2,6,6,-tetramethylpiperidine 1-oxide (TEMPO) is shown to be a mild and efficient approach to the title uronates. In the gluco, galacto, allo, and 2-acetamido-2-deoxy-gluco series, the corresponding β- or α- and β-glycosyl azides could be smoothly oxidised and alternative preparations are compared to this access.

Original languageEnglish
Pages (from-to)85-92
Number of pages8
JournalCarbohydrate Research
Volume268
Issue number1
DOIs
Publication statusPublished - Mar 1 1995

Keywords

  • (d-Glycopyranosyl azide)uronates
  • Glycosyl azides
  • NaOC1-TEMPO oxidation

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Organic Chemistry

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