Synthesis of functionalized para -and meta -terphenyls based on site-selective Suzuki cross-coupling reactions of bis(triflates) of methyl 2,5-dihydroxybenzoate and methyl 2,4-dihydroxybenzoate

Muhammad Nawaz, Ihsan Ullah, Obaid Ur Rahman Abid, Asad Ali, T. Patonay, Ashot S. Saghyan, Tariel V. Ghochikan, Alexander Villinger, Peter Langer

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The palladium(0)-catalyzed Suzuki cross-coupling reaction of the bis(triflates) of methyl 2,5-dihydroxybenzoate and methyl 2,4-dihydroxybenzoate afforded para-and meta-terphenyls, respectively. The reactions proceeded with very good site selectivity in favor of the sterically less hindered carbon atom.

Original languageEnglish
Pages (from-to)1048-1058
Number of pages11
JournalCanadian Journal of Chemistry
Volume91
Issue number11
DOIs
Publication statusPublished - Nov 2013

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Palladium
Carbon
Atoms
methyl triflate
2,5-dihydroxybenzoic acid
beta-resorcylic acid

Keywords

  • Cross-coupling
  • Palladium
  • Site selectivity
  • Suzuki reaction
  • Terphenyls

ASJC Scopus subject areas

  • Chemistry(all)
  • Organic Chemistry
  • Catalysis

Cite this

Synthesis of functionalized para -and meta -terphenyls based on site-selective Suzuki cross-coupling reactions of bis(triflates) of methyl 2,5-dihydroxybenzoate and methyl 2,4-dihydroxybenzoate. / Nawaz, Muhammad; Ullah, Ihsan; Abid, Obaid Ur Rahman; Ali, Asad; Patonay, T.; Saghyan, Ashot S.; Ghochikan, Tariel V.; Villinger, Alexander; Langer, Peter.

In: Canadian Journal of Chemistry, Vol. 91, No. 11, 11.2013, p. 1048-1058.

Research output: Contribution to journalArticle

Nawaz, Muhammad ; Ullah, Ihsan ; Abid, Obaid Ur Rahman ; Ali, Asad ; Patonay, T. ; Saghyan, Ashot S. ; Ghochikan, Tariel V. ; Villinger, Alexander ; Langer, Peter. / Synthesis of functionalized para -and meta -terphenyls based on site-selective Suzuki cross-coupling reactions of bis(triflates) of methyl 2,5-dihydroxybenzoate and methyl 2,4-dihydroxybenzoate. In: Canadian Journal of Chemistry. 2013 ; Vol. 91, No. 11. pp. 1048-1058.
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AU - Patonay, T.

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AU - Ghochikan, Tariel V.

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KW - Terphenyls

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