Synthesis of ferrocene amides and α-ketoamides via palladium-catalyzed homogeneous carbonylation reaction

Zsolt Szarka, R. Skoda-Földes, Árpád Kuik, Z. Berente, L. Kollár

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

New ferrocene α-ketoamides and various ferrocene amides have been synthesized in good yields via homogeneous catalytic carbonylation of iodoferrocene in the presence of secondary amines as nucleophiles. With sterically less hindered amines, the appropriate choice of conditions made it possible to produce either the amides or the α-ketoamides with good selectivity. The reaction of amines with sterically hindered amino groups led to the amides as main products.

Original languageEnglish
Pages (from-to)545-550
Number of pages6
JournalSynthesis
Issue number4
Publication statusPublished - 2003

Fingerprint

Carbonylation
Palladium
Amides
Amines
Nucleophiles
ferrocene

Keywords

  • Carbonylations
  • Catalysis
  • Ferrocene α-ketoamides
  • Ferrocene amides
  • Palladium

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Synthesis of ferrocene amides and α-ketoamides via palladium-catalyzed homogeneous carbonylation reaction. / Szarka, Zsolt; Skoda-Földes, R.; Kuik, Árpád; Berente, Z.; Kollár, L.

In: Synthesis, No. 4, 2003, p. 545-550.

Research output: Contribution to journalArticle

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AU - Szarka, Zsolt

AU - Skoda-Földes, R.

AU - Kuik, Árpád

AU - Berente, Z.

AU - Kollár, L.

PY - 2003

Y1 - 2003

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