D-glükóz-alapú, foszfonoalkil-oldalláncot tartalmazó azakorona-éterek szintézise és alkalmazása enantioszelektív reakciókban

Translated title of the contribution: Synthesis of D-glucose-based azacrown ethers with phosphonoalkyl side chain and their application to enantioselective reaction

Research output: Contribution to journalArticle

Abstract

Chiral α-D-glucose-based monoaza-15-crown-5 ethers with phosphonoalkyl side chain (5a-e) have been synthesised. The substituent at the nitrogen atom had a major influence on the cation binding ability of the azacrown. The new lariat ethers (5a-e) showed significant asymmetic induction as phase transfer catalysts in the Michael addition of 2-nitropropane to chalcone.

Original languageHungarian
Pages (from-to)171-176
Number of pages6
JournalMagyar Kemiai Folyoirat, Kemiai Kozlemenyek
Volume106
Issue number4
Publication statusPublished - 2000

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Ethers
Chalcone
Glucose
Cations
Nitrogen
Atoms
Catalysts
2-nitropropane
15-crown-5

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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title = "D-gl{\"u}k{\'o}z-alap{\'u}, foszfonoalkil-oldall{\'a}ncot tartalmaz{\'o} azakorona-{\'e}terek szint{\'e}zise {\'e}s alkalmaz{\'a}sa enantioszelekt{\'i}v reakci{\'o}kban",
abstract = "Chiral α-D-glucose-based monoaza-15-crown-5 ethers with phosphonoalkyl side chain (5a-e) have been synthesised. The substituent at the nitrogen atom had a major influence on the cation binding ability of the azacrown. The new lariat ethers (5a-e) showed significant asymmetic induction as phase transfer catalysts in the Michael addition of 2-nitropropane to chalcone.",
author = "Tibor Nov{\'a}k and P. Bak{\'o} and G. Keglevich and K. Lud{\'a}nyi and L. Tőke",
year = "2000",
language = "Hungarian",
volume = "106",
pages = "171--176",
journal = "Magyar Kemiai Folyoirat, Kemiai Kozlemenyek",
issn = "1418-9933",
publisher = "Magyar Kemikusok Egyesulete/Hungarian Chemical Society",
number = "4",

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TY - JOUR

T1 - D-glükóz-alapú, foszfonoalkil-oldalláncot tartalmazó azakorona-éterek szintézise és alkalmazása enantioszelektív reakciókban

AU - Novák, Tibor

AU - Bakó, P.

AU - Keglevich, G.

AU - Ludányi, K.

AU - Tőke, L.

PY - 2000

Y1 - 2000

N2 - Chiral α-D-glucose-based monoaza-15-crown-5 ethers with phosphonoalkyl side chain (5a-e) have been synthesised. The substituent at the nitrogen atom had a major influence on the cation binding ability of the azacrown. The new lariat ethers (5a-e) showed significant asymmetic induction as phase transfer catalysts in the Michael addition of 2-nitropropane to chalcone.

AB - Chiral α-D-glucose-based monoaza-15-crown-5 ethers with phosphonoalkyl side chain (5a-e) have been synthesised. The substituent at the nitrogen atom had a major influence on the cation binding ability of the azacrown. The new lariat ethers (5a-e) showed significant asymmetic induction as phase transfer catalysts in the Michael addition of 2-nitropropane to chalcone.

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M3 - Article

VL - 106

SP - 171

EP - 176

JO - Magyar Kemiai Folyoirat, Kemiai Kozlemenyek

JF - Magyar Kemiai Folyoirat, Kemiai Kozlemenyek

SN - 1418-9933

IS - 4

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