Synthesis of chiral 1,3-calix[4](crown-6) ethers as potential mediators for asymmetric recognition processes

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Abstract

Novel chromogenic 1,3-calix[4](crown-6) derivatives comprised of 1,1′-binaphthyl-, methyl-α-D-glucoside-and D-mannitol moieties in the crown ether ring have been synthesized. UV-vis spectroscopic measurements of the 2,4-dinitrophenylazo chromogenic molecules indicated noticeable chiral discrimination associated with coloration towards primary amine enantiomers.

Original languageEnglish
Pages (from-to)1025-1035
Number of pages11
JournalTetrahedron Asymmetry
Volume14
Issue number8
DOIs
Publication statusPublished - Apr 18 2003

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ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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