Synthesis of achiral and new chiral crown ethers containing a triphenylphosphane unit

Tamás Szabó, László Petri, Szilveszter Gergely, Péter Huszthy

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2 Citations (Scopus)

Abstract

Synthesis and characterization of achiral 1 and new chiral macrocycles (R,R)-2, (S,S)-3 and (S,S)-4 containing a triphenylphosphanone unit have been accomplished. A new method was used for the reduction of phosphanones to phosphanes. Using this method new potential catalyst ligands 15, (R,R)-16, (S,S)-17 and (S,S)-18 containing a triphenylphosphane unit were synthesized and characterized. These ligands are promising candidates for coordination chemistry studies and homogeneous catalytic reactions.

Original languageEnglish
Pages (from-to)20-33
Number of pages14
JournalArkivoc
Volume2015
Issue number5
DOIs
Publication statusPublished - Feb 5 2015

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Keywords

  • Crown ethers
  • Macrocycles
  • Triarylphosphanes
  • Triarylphosphanones

ASJC Scopus subject areas

  • Organic Chemistry

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