Synthesis of a phenyl β-avobioside derivative of the dissacharide component of avoparcins

Xia Dong, Francçois Tillequin, Claude Monneret, Géza Horvath, Ferenc Sztaricskai

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The synthesis of the phenyl β-glycoside of avobiose, a disaccharide fragment present in the antibiotic avoparcin, is reported1. It is based on glycosylation of phenyl 3,4,6-tri-O-benzyl-β-d-glucopyranoside with 2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-l-ribo-hex-1-enitol, a fully protected glycal of l-ristosamine, in the presence of trimethylsilyl triflate.

Original languageEnglish
Pages (from-to)107-115
Number of pages9
JournalCarbohydrate Research
Volume232
Issue number1
DOIs
Publication statusPublished - Jul 20 1992

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Organic Chemistry

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