Synthesis and utilization of α-aminophosphine oxides and related derivatives

Erika Bálint, Anna Tripolszky, Anna Ádám, Ádám Tajti, G. Keglevich

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Abstract

Themicrowave-assisted synthesis of mono- and bis(aminophosphine oxides)was studied using various secondary phosphine oxides as the P-reagent in condensation with paraformaldehyde and primary amines. After double deoxygenation, the bis-products were utilized as bidentate phosphine ligands in the synthesis of platinum complexes. α-Aryl-α-aminophosphine oxides and α-aryl-α-aminophosphonates were also prepared by the addition of >P(O)H species to imines.

Original languageEnglish
Pages (from-to)1539-1540
Number of pages2
JournalPhosphorus, Sulfur and Silicon and the Related Elements
Volume191
Issue number11-12
DOIs
Publication statusPublished - Dec 1 2016

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Keywords

  • Kabachnik–Fields reaction
  • microwave
  • Pudovik reaction
  • transition metal complexes
  • α-Aminophosphine oxides
  • α-aminophosphonates

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Inorganic Chemistry

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