Synthesis and utilization of α-aminophosphine oxides and related derivatives

Erika Bálint, Anna Tripolszky, Anna Ádám, Ádám Tajti, G. Keglevich

Research output: Contribution to journalArticle

Abstract

Themicrowave-assisted synthesis of mono- and bis(aminophosphine oxides)was studied using various secondary phosphine oxides as the P-reagent in condensation with paraformaldehyde and primary amines. After double deoxygenation, the bis-products were utilized as bidentate phosphine ligands in the synthesis of platinum complexes. α-Aryl-α-aminophosphine oxides and α-aryl-α-aminophosphonates were also prepared by the addition of >P(O)H species to imines.

Original languageEnglish
Pages (from-to)1539-1540
Number of pages2
JournalPhosphorus, Sulfur and Silicon and the Related Elements
Volume191
Issue number11-12
DOIs
Publication statusPublished - Dec 1 2016

Fingerprint

phosphine
Oxides
Derivatives
Imines
Platinum
Amines
Condensation
Ligands

Keywords

  • Kabachnik–Fields reaction
  • microwave
  • Pudovik reaction
  • transition metal complexes
  • α-Aminophosphine oxides
  • α-aminophosphonates

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Synthesis and utilization of α-aminophosphine oxides and related derivatives. / Bálint, Erika; Tripolszky, Anna; Ádám, Anna; Tajti, Ádám; Keglevich, G.

In: Phosphorus, Sulfur and Silicon and the Related Elements, Vol. 191, No. 11-12, 01.12.2016, p. 1539-1540.

Research output: Contribution to journalArticle

Bálint, Erika ; Tripolszky, Anna ; Ádám, Anna ; Tajti, Ádám ; Keglevich, G. / Synthesis and utilization of α-aminophosphine oxides and related derivatives. In: Phosphorus, Sulfur and Silicon and the Related Elements. 2016 ; Vol. 191, No. 11-12. pp. 1539-1540.
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