SnO2-montmorillonit-nanokompozitok szintézise és szerkezeti paraméterei

Translated title of the contribution: Synthesis and structural parameters of SnO2-montmorillonite nanocomposites

Research output: Contribution to journalArticle

Abstract

Tin(IV) oxide nanoparticles were prepared by wet colloidchemical synthesis method on the surface of layered montmorillonite support. The prepared nanocomposites were investigated by several independent measurement methods. The X-ray diffraction, the Mössbauer spectroscopy and the positron lifetime spectroscopy examinations squarely demonstrated the intercalation of the nanosized SnO2 particles into the montmorillonite. It was also established that the size of the nanoparticles can be controlled well by the principles of Weimarn's law. N2 gas adsorption experiments evinced that the incorporation of the SnO2 nanoparticles causes a significant increase in the specific surface area and the porosity of montmorillonite. During the thermoanalytical measurements the heat and weight changes of the samples were followed. By these results the optimal calcination temperature of the nanocomposites (400 °C) was obtained. We also observed that the presence of the tin oxide nanoparticles has a strong effect on the form of the TG and the DTA curves.

Original languageHungarian
Pages (from-to)148-159
Number of pages12
JournalMagyar Kemiai Folyoirat, Kemiai Kozlemenyek
Volume108
Issue number3
Publication statusPublished - Mar 2002

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Bentonite
Nanocomposites
Nanoparticles
Spectroscopy
Gas adsorption
Positrons
Intercalation
Tin oxides
Specific surface area
Calcination
Differential thermal analysis
Porosity
X ray diffraction
Experiments
Temperature

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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title = "SnO2-montmorillonit-nanokompozitok szint{\'e}zise {\'e}s szerkezeti param{\'e}terei",
abstract = "Tin(IV) oxide nanoparticles were prepared by wet colloidchemical synthesis method on the surface of layered montmorillonite support. The prepared nanocomposites were investigated by several independent measurement methods. The X-ray diffraction, the M{\"o}ssbauer spectroscopy and the positron lifetime spectroscopy examinations squarely demonstrated the intercalation of the nanosized SnO2 particles into the montmorillonite. It was also established that the size of the nanoparticles can be controlled well by the principles of Weimarn's law. N2 gas adsorption experiments evinced that the incorporation of the SnO2 nanoparticles causes a significant increase in the specific surface area and the porosity of montmorillonite. During the thermoanalytical measurements the heat and weight changes of the samples were followed. By these results the optimal calcination temperature of the nanocomposites (400 °C) was obtained. We also observed that the presence of the tin oxide nanoparticles has a strong effect on the form of the TG and the DTA curves.",
author = "J. N{\'e}meth and I. D{\'e}k{\'a}ny and K. S{\"u}vegh and A. V{\'e}rtes and T. Marek and Z. Klencs{\'a}r",
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T1 - SnO2-montmorillonit-nanokompozitok szintézise és szerkezeti paraméterei

AU - Németh, J.

AU - Dékány, I.

AU - Süvegh, K.

AU - Vértes, A.

AU - Marek, T.

AU - Klencsár, Z.

PY - 2002/3

Y1 - 2002/3

N2 - Tin(IV) oxide nanoparticles were prepared by wet colloidchemical synthesis method on the surface of layered montmorillonite support. The prepared nanocomposites were investigated by several independent measurement methods. The X-ray diffraction, the Mössbauer spectroscopy and the positron lifetime spectroscopy examinations squarely demonstrated the intercalation of the nanosized SnO2 particles into the montmorillonite. It was also established that the size of the nanoparticles can be controlled well by the principles of Weimarn's law. N2 gas adsorption experiments evinced that the incorporation of the SnO2 nanoparticles causes a significant increase in the specific surface area and the porosity of montmorillonite. During the thermoanalytical measurements the heat and weight changes of the samples were followed. By these results the optimal calcination temperature of the nanocomposites (400 °C) was obtained. We also observed that the presence of the tin oxide nanoparticles has a strong effect on the form of the TG and the DTA curves.

AB - Tin(IV) oxide nanoparticles were prepared by wet colloidchemical synthesis method on the surface of layered montmorillonite support. The prepared nanocomposites were investigated by several independent measurement methods. The X-ray diffraction, the Mössbauer spectroscopy and the positron lifetime spectroscopy examinations squarely demonstrated the intercalation of the nanosized SnO2 particles into the montmorillonite. It was also established that the size of the nanoparticles can be controlled well by the principles of Weimarn's law. N2 gas adsorption experiments evinced that the incorporation of the SnO2 nanoparticles causes a significant increase in the specific surface area and the porosity of montmorillonite. During the thermoanalytical measurements the heat and weight changes of the samples were followed. By these results the optimal calcination temperature of the nanocomposites (400 °C) was obtained. We also observed that the presence of the tin oxide nanoparticles has a strong effect on the form of the TG and the DTA curves.

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