Synthesis and reduction of carbohydrate benzylidene hemithioacetal diastereomers with LiAlH4-AlCl3

Peter Fugedi, András Lipták

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Reduction of methyl 2-O-benzyl-endo- (11) and -exo-3-O-4-S-benzylidene-4,6- dideoxy-4-thio-α-D-galactopyranoside (12) gives the same S-benzyl derivative (6), but with very different reaction rates, indicating that the configuration of the acetal carbon considerably influences the reactivity of the acetal oxygen atoms.

Original languageEnglish
Pages (from-to)1234-1235
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number24
DOIs
Publication statusPublished - Jan 1 1980

ASJC Scopus subject areas

  • Molecular Medicine

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