Abstract
Reduction of methyl 2-O-benzyl-endo- (11) and -exo-3-O-4-S-benzylidene-4,6- dideoxy-4-thio-α-D-galactopyranoside (12) gives the same S-benzyl derivative (6), but with very different reaction rates, indicating that the configuration of the acetal carbon considerably influences the reactivity of the acetal oxygen atoms.
| Original language | English |
|---|---|
| Pages (from-to) | 1234-1235 |
| Number of pages | 2 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 24 |
| Publication status | Published - 1980 |
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ASJC Scopus subject areas
- Molecular Medicine
Cite this
Synthesis and reduction of carbohydrate benzylidene hemithioacetal diastereomers with LiAlH4-AlCl3 . / Fugedi, Peter; Lipták, A.
In: Journal of the Chemical Society, Chemical Communications, No. 24, 1980, p. 1234-1235.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis and reduction of carbohydrate benzylidene hemithioacetal diastereomers with LiAlH4-AlCl3
AU - Fugedi, Peter
AU - Lipták, A.
PY - 1980
Y1 - 1980
N2 - Reduction of methyl 2-O-benzyl-endo- (11) and -exo-3-O-4-S-benzylidene-4,6- dideoxy-4-thio-α-D-galactopyranoside (12) gives the same S-benzyl derivative (6), but with very different reaction rates, indicating that the configuration of the acetal carbon considerably influences the reactivity of the acetal oxygen atoms.
AB - Reduction of methyl 2-O-benzyl-endo- (11) and -exo-3-O-4-S-benzylidene-4,6- dideoxy-4-thio-α-D-galactopyranoside (12) gives the same S-benzyl derivative (6), but with very different reaction rates, indicating that the configuration of the acetal carbon considerably influences the reactivity of the acetal oxygen atoms.
UR - http://www.scopus.com/inward/record.url?scp=37049099827&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=37049099827&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:37049099827
SP - 1234
EP - 1235
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 24
ER -