Synthesis and rearrangement of 13-thiaprostanoids

L. Novák, P. Kolonits, Cs Szántay, Aszódi, M. Kajtár-Peredy

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Abstract

Thiaprostanoids 13 were prepared by conjugate addition of mercaptane 6 to cyclopentenones 12 and 20. Novel rearrangements of these compounds to 14 and 15 were interpreted as enolate induced [1,5]-sigmatropic shift on the corresponding dehydration products 16. Preparation of the various substrates and structural elucidation of new products are described.

Original languageEnglish
Pages (from-to)153-159
Number of pages7
JournalTetrahedron
Volume38
Issue number1
DOIs
Publication statusPublished - 1982

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Dehydration
Substrates
cyclopentenone

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Synthesis and rearrangement of 13-thiaprostanoids. / Novák, L.; Kolonits, P.; Szántay, Cs; Aszódi, ; Kajtár-Peredy, M.

In: Tetrahedron, Vol. 38, No. 1, 1982, p. 153-159.

Research output: Contribution to journalArticle

Novák, L. ; Kolonits, P. ; Szántay, Cs ; Aszódi, ; Kajtár-Peredy, M. / Synthesis and rearrangement of 13-thiaprostanoids. In: Tetrahedron. 1982 ; Vol. 38, No. 1. pp. 153-159.
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