Synthesis and rearrangement of 13-thiaprostanoids

L. Novák, P. Kolonits, Cs Szántay, Aszódi, M. Kajtár

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Thiaprostanoids 13 were prepared by conjugate addition of mercaptane 6 to cyclopentenones 12 and 20. Novel rearrangements of these compounds to 14 and 15 were interpreted as enolate induced [1,5]-sigmatropic shift on the corresponding dehydration products 16. Preparation of the various substrates and structural elucidation of new products are described.

Original languageEnglish
Pages (from-to)153-159
Number of pages7
JournalTetrahedron
Volume38
Issue number1
DOIs
Publication statusPublished - 1982

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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