Synthesis and reactions of paramagnetic aromatic aldehydes as useful synthetic building blocks

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Abstract

Starting from paramagnetic benzaldehyde, a benzophenone-type photoactivable spin label, paramagnetic warfarin and phenindione were synthesized. Nitration of protected benzylic alcohol led to 2-nitrobenzylmethanethiosulfonate, a thiol specific spin label, and 2-nitroaldehyde, which was a key compound for paramagnetic indigo, salicylic acid and nifedipine.

Original languageEnglish
Pages (from-to)2115-2120
Number of pages6
JournalSynthesis
Issue number13
DOIs
Publication statusPublished - Sep 6 2004

Keywords

  • Anticoagulant
  • Drugs
  • Free radicals
  • Indole
  • Pyridines

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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