Synthesis and modification reaction of organoboron segmented block copolymer of allyl-telechelic poly(isobutylene)

Mamoru Miyata, Frauke Meyer, Yoshiki Chujo, Péter Werner Groh, B. Iván

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Hydroboration polymerization of low molecular weight allyl-telechelic polyisobutylene with narrow molecular weight distribution gave a novel stable organoboron segmented block copolymer by using tripylborane as a boron monomer. The chain transformation reaction of the copolymer was also examined. The reaction with α,α-dichloromethyl methyl ether (DCME) gave the corresponding polyisobutylene segmented poly(alcohol).

Original languageEnglish
Pages (from-to)25-31
Number of pages7
JournalPolymer Bulletin
Volume52
Issue number1
Publication statusPublished - Jun 2004

Fingerprint

polyisobutylene
butenes
Molecular weight distribution
block copolymers
Block copolymers
Boron
Ethers
Alcohols
Copolymers
Monomers
Molecular weight
Polymerization
hydroboration
Methyl Ethers
low molecular weights
synthesis
molecular weight
ethers
copolymers
boron

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

Cite this

Synthesis and modification reaction of organoboron segmented block copolymer of allyl-telechelic poly(isobutylene). / Miyata, Mamoru; Meyer, Frauke; Chujo, Yoshiki; Groh, Péter Werner; Iván, B.

In: Polymer Bulletin, Vol. 52, No. 1, 06.2004, p. 25-31.

Research output: Contribution to journalArticle

Miyata, Mamoru ; Meyer, Frauke ; Chujo, Yoshiki ; Groh, Péter Werner ; Iván, B. / Synthesis and modification reaction of organoboron segmented block copolymer of allyl-telechelic poly(isobutylene). In: Polymer Bulletin. 2004 ; Vol. 52, No. 1. pp. 25-31.
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