Synthesis and infrared and Mössbauer studies of Eu(III) complexes with cyanoxime anions

N. Gerasimchuk, E. Kuzmann, A. Büki, A. Vértes, L. Nagy, K. Burger

Research output: Contribution to journalArticle

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Abstract

A series of europium(III) complexes with cyanoxime ligands were prepared. The IR spectroscopic data revealed that the ambidentate ligands were coordinated to the central europium(III) atom in either a tridentate or a bidentate manner. The Mössbauer isomer shift (IS) values showed a correlation with the quadrupole splitting (QS) values in all complexes. A plot of the IS values versus the QS values showed that with increasing electron density of the Eu(III) nucleus the symmetry of the electronic shell around the Eu(III) atom decreases.

Original languageEnglish
Pages (from-to)45-50
Number of pages6
JournalInorganica Chimica Acta
Volume188
Issue number1
DOIs
Publication statusPublished - Oct 1 1991

Fingerprint

Europium
europium
Isomers
Anions
Negative ions
isomers
quadrupoles
Ligands
anions
Infrared radiation
Atoms
ligands
shift
synthesis
Carrier concentration
atoms
plots
Electrons
nuclei
symmetry

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Synthesis and infrared and Mössbauer studies of Eu(III) complexes with cyanoxime anions. / Gerasimchuk, N.; Kuzmann, E.; Büki, A.; Vértes, A.; Nagy, L.; Burger, K.

In: Inorganica Chimica Acta, Vol. 188, No. 1, 01.10.1991, p. 45-50.

Research output: Contribution to journalArticle

Gerasimchuk, N. ; Kuzmann, E. ; Büki, A. ; Vértes, A. ; Nagy, L. ; Burger, K. / Synthesis and infrared and Mössbauer studies of Eu(III) complexes with cyanoxime anions. In: Inorganica Chimica Acta. 1991 ; Vol. 188, No. 1. pp. 45-50.
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