Synergetic of pt nanoparticles and h-zsm-5 zeolites for efficient CO2 activation: Role of interfacial sites in high activity

András Sápi, Upendar Kashaboina, Kornélia B. Ábrahámné, Juan Fernando Gómez-Pérez, Imre Szenti, Gyula Halasi, János Kiss, Balázs Nagy, Tamás Varga, Á. Kukovecz, Z. Kónya

Research output: Contribution to journalArticle

Abstract

Catalytic systems prepared by controlled processes play an important role in the utilization of CO2 via catalytic hydrogenation to produce useful C1 chemicals (such as CO, CH4, and CH3OH), which will be vital for forthcoming applications in energy conversion and storage. Size-controlled Pt nanoparticles were prepared by a polyol method and deposited on H-ZSM-5 (SiO2/Al2O3 = 30, 80, and 280) zeolite supports. The prepared catalysts were tested for the CO2 hydrogenation in the temperature range of T = 473–873 K and ambient pressure, with CO2/H2 = 1:4. Size-controlled Pt nanoparticles boosted the catalytic activity of the pure H-ZSM-5 zeolites resulted in ~16 times higher CO2 consumption rate. The activity were ~4 times higher and CH4 selectivity at 873 K was ~12 times higher over 0.5% Pt/H-ZSM-5 (SiO2/Al2O3 = 30) compared to 0.5% Pt/H-ZSM-5 (SiO2/Al2O3 = 280). In-situ DRIFTS studies assuming the presence of a surface complex in which the CO is perturbed by hydrogen and adsorbes via C-end on Pt but the oxygen tilts to the protons of the zeolite support.

Original languageEnglish
Article number127
JournalFrontiers in Materials
Volume6
DOIs
Publication statusPublished - May 29 2019

Fingerprint

Zeolites
Hydrogenation
Chemical activation
Carbon Monoxide
Nanoparticles
Polyols
Energy conversion
Catalyst supports
Energy storage
Catalyst activity
Protons
Hydrogen
Catalysts
Oxygen
Temperature

Keywords

  • CO activation
  • Controlled size Pt
  • Drifts
  • Heterogeneous catalysis
  • Mechanisms
  • Zeolites

ASJC Scopus subject areas

  • Materials Science (miscellaneous)

Cite this

Synergetic of pt nanoparticles and h-zsm-5 zeolites for efficient CO2 activation : Role of interfacial sites in high activity. / Sápi, András; Kashaboina, Upendar; Ábrahámné, Kornélia B.; Gómez-Pérez, Juan Fernando; Szenti, Imre; Halasi, Gyula; Kiss, János; Nagy, Balázs; Varga, Tamás; Kukovecz, Á.; Kónya, Z.

In: Frontiers in Materials, Vol. 6, 127, 29.05.2019.

Research output: Contribution to journalArticle

Sápi, András ; Kashaboina, Upendar ; Ábrahámné, Kornélia B. ; Gómez-Pérez, Juan Fernando ; Szenti, Imre ; Halasi, Gyula ; Kiss, János ; Nagy, Balázs ; Varga, Tamás ; Kukovecz, Á. ; Kónya, Z. / Synergetic of pt nanoparticles and h-zsm-5 zeolites for efficient CO2 activation : Role of interfacial sites in high activity. In: Frontiers in Materials. 2019 ; Vol. 6.
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AU - Szenti, Imre

AU - Halasi, Gyula

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